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SECTION I - PRODUCT IDENTIFICATION
Sigma Chemical Company Emergency Phone: 314-771-5765 PO Box 15408 Phone: 800-325-3010 St. Louis MO 63178 Fax: 800-325-5052 Chemical Identification Product#: 53379 NAME:Sodium Iodide Anhydrous
SECTION II - COMPOSITION/INFORMATION ON INGREDIENTS
CAS #: 7681-82-5 MF: TINAI
SYNONYMS:
ANAYODIN * IODURIL * JODID SODNY (CZECH) * NATRIUMJODID (GERMAN) * SODIUM IODINE * SODIUM MONOIODIDE *
SECTION III - HAZARDS IDENTIFICATION
LABEL PRECAUTIONARY STATEMENTS:
HARMFUL
HARMFUL BY INHALATION IN CONTACT WITH SKIN AND IF SWALLOWED.
IRRITATING TO EYES AND SKIN.
MAY CAUSE SENSITIZATION BY INHALATION AND SKIN CONTACT
POSSIBLE RISK OF IRREVERSIBLE EFFECTS.
POSSIBLE TERATOGEN.
TARGET ORGAN(S): THYROID
DO NOT BREATHE DUST.
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE
WEAR SUITABLE PROTECTIVE CLOTHING.
SECTION IV - FIRST AID MEASURES
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF WATER.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
SECTION V - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA:
NONE COMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES.
UNUSUAL FIRE AND EXPLOSIONS HAZARDS:
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
SECTION VI - ACCIDENTAL RELEASE MEASURES
WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY RUBBER GLOVES.
SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL.
AVOID RAISING DUST
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
SECTION VII - HANDLING AND STORAGE
REFER TO SECTION VIII
SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION
WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING.
SAFETY SHOWER AND EYE BATH.
MECHANICAL EXHAUST REQUIRED
D0 NOT BREATHE DUST.
AVOID CONTACT WITH EYES, ON SKIN, AND CLOTHING.
AVOID PROLONGED OR REPEATED EXPOSURE.
WASH THOROUGHLY AFTER HANDLING.
HARMFUL SOLID.
IRRITANT.
POSSIBLE TERATOGEN.
SENSITIZER.
KEEP TIGHTLY CLOSED.
MOISTURE SENSITIVE
AIR AND LIGHT SENSITIVE
STORE UNDER NITROGEN.
STORE IN A COOL DRY PLACE.
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE AND ODOR:
WHITE POWDER
MELTING POINT: 661 C
VAPOR DENSITY: >1
SPECIFIC GRAVITY: 3.667
SECTION X - STABILITY AND REACTIVITY
STRONG ACIDS
LIGHT SENSITIVE
AIR SENSITIVE
MOISTURE SENSITIVE
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS:
TOXIC FUMES OF:
HYDROGEN IODIDE
SODIUM/SODIUM OXIDES
SECTION XI - TOXICOLOGICAL INFORMATION
ACUTE EFFECTS:
HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN.
CAUSES EYE AND SKIN IRRITATION.
MAY CAUSE ALLERGIC RESPIRATORY AND SKIN REACTIONS.
TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
CHRONIC EFFECTS:
OVEREXPOSURE MAY CAUSE REPRODUCTIVE DISORDER(S) BASED ON TESTS WITH LABORATORY ANIMALS.
TARGET ORGAN (S): THYROID
ADDITIONAL INFORMATION:
PROLONGED EXPOSURE TO IODIDES MAY PRODUCE IODISM IN SENSITIVE INDIVIDUALS. SYMPTOMS OF EXPOSURE INCLUDE: SKIN RASH, RUNNING NOSE, HEADACHE AND IRRITATION OF THE MUCOUS MEMBRANES. FOR SEVERE CASES THE SKIN MAY SHO PIMPLES, BOILS, HIVES, BLISTERS AND BLACK AND BLUE SPOTS.
RTECS NO: WD6475000
SODIUM IODIDE
IRRITATION DATA: SKN-RBT 500 MG/24h MOD 28ZPAK -,21,72 EYE-RBT 100 MG/24H MOD 28ZPAK -,21,72 TOXICITY DATA: ORL-RAT LD50:4340 MG/KG 28ZPAK -.21,72 IVN-RAT LD50:1060 MG/KG AEPPAE 222,584,54 ORL-MUS LD50:1 GM/KG 85GMAT -,105,82
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATION.
SECTION XII - ECOLOGICAL INFORMATION
DATA NOT YET AVAILABLE.
SECTION XIII - DISPOSAL CONSIDERATIONS
FOR SMALL QUANTITIES: CAUTIOUSLY ADD TO A LARGE STIRRED EXCESS OF WATER. ADJUST THE PH TO NEUTRAL, SEPARATE ANY INSOLUBLE SOLIDS OR LIQUIDS AND PACKAGE THEM FOR HAZARDOUS-WASTE DISPOSAL. FLUSH THE AQUEOUS SOLUTION DOWN THE DRAIN WITH PLENTY OF WATER. THE HYDROLYSIS AND NEUTRALIZATION REACTIONS MAY GENERATE HEAT AND FUMES WHICH CAN BE CONTROLLED BY THE RATE OF ADDITION.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
SECTION XIV - TRANSPORT INFORMATION
CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
SECTION XV - REGULATORY INFORMATION
REVIEWS, STANDARDS, AND REGULATIONS:
NOHS 1974: HZD 60120: NIS 7: TNF 529: NOS 9: TNE 6918 NOES 1983: HZD 60120: NIS 12: TNF 1758: NOS 26; TNE 63005: TFE 49300 EPA TSCA CHEMICAL INVENTORY, JUNE 1993
SECTION XVI - OTHER INFORMATION
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
COPYRIGHT 1994 SIGMA CHEMICAL C0., INC.
LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.