|16a||Last Update: 12/23/99|
Numerous reports have appeared describing the Sick Building Syndrome which was been associated with the quality of indoor air in public buildings. Building related health problems may be due to contamination of indoor air by emissions of volatile organic compounds (VOC's) from a variety of sources including construction materials, fabrics, furnishings, maintenance supplies, combustion by-products, adhesives, paints, caulks, paper and cleaning products. Recently new allegations have appeared suggesting increased danger to the population and especially to children from second hand smoke from cigarettes. Because many of the volatile emissions and by-products from these products are toxic, additional knowledge of the levels of these organic chemicals in the indoor air environment is required in order to determine the human health impacts. In the next few years, it is expected that the quality of indoor air will come under closer scrutiny by the public in both the domestic home and industrial workplace environments. New methods will be required to accurately determine the identity and to accurately quantify the levels of these volatile organics in indoor air samples. Likewise, additional studies will be needed to determine the sources of the air contamination and manufacturing processes improved to limit the emission of VOC's from these manufactured products.
The Scientific Instrument Services Short Path Thermal Desorption system was used in conjunction with adsorbent traps packed with Tenax® TA (TM) adsorbent resin to trap the VOC's in air samples for subsequent analysis via GC/MS. The technique has proven to be extremely versatile for the analysis of air samples to detect and identify organics in air in concentration ranges from parts per hundred (pph) to sub parts per billion (ppb). Air samples from 1 ml up through 100 liters are pumped through the absorbent trap using a small industrial hygiene pump to trap the volatiles on the adsorbent trap. After the VOC's and semi-volatiles are trapped, they are thermally extracted from the adsorbent resins using the Short Path Thermal Desorption System. This technique uses a combination of ballistic heating and purging of pure GC carrier gas through the adsorbent resin to extract the VOC's, as well as many semi-volatiles from the resin trap and onto the GC column for subsequent analysis. Solid samples, as vinyl flooring, are placed in an enclosed environment, purged with air to trap the volatile emissions on the adsorbent traps and then analyzed in the same manner as the air samples. This technique can be utilized for both the qualitative and quantitative analysis of VOC's and semi-volatiles in indoor air, as well as outdoor air samples.
A Short Path Thermal Desorption System Model TD-2 (Scientific Instrument Services, Ringoes, NJ) was attached to the injection port of a Hewlett Packard 5890 Series II GC and 5971 Mass Selective Detector. The desorption system has been fully described in previous publications (1,2,3). The desorption heater blocks were maintained at 250 degrees C for the desorption process and the desorption time was set to 10 minutes. The mass spectrometer was operated in the electron impact mode (EI) at 70 eV and scanned from mass 35 to mass 350 during the GC run to identify all the components. The data was interpreted and the peaks identified via the Wiley NBS library using the H.P. ChemStation software.
The GC column consisted of a 30 meter DB5-MS (J&W) capillary column, 0.25 mm I.D. x 0.5 micron film thickness. A 0.5 meter deactivated megabore (0.53 mm I.D.) fused silica guard column was used at the front of the GC column. The pressure programmed injection port of the GC was operated at 250 degrees C and used in the splitless mode at a column flow rate of 1.0 ml/min. The GC oven was maintained at -40 degrees C during the desorption process after which it was programmed from -40 degrees C to 150 at 4 degrees /min and then programmed at 10 degrees /minute to 300 degrees C.
Figure 1 - Short Path Thermal Desorption System
The desorption sample tubes consist of 1/4 in. O.D. by 4.0 in. long glass lined stainless steel tubes packed with 200 milligrams of Tenax TA (TM) between two glass wool plugs. Before use, the desorption tubes with adsorbent resins were conditioned in the desorption tube conditioning oven (Scientific Instrument Services, Ringoes, NJ) at a temperature of 300 degrees C for 4 hours with a 10 ml/min flow of high purity nitrogen through the adsorbent resin. This assures that the traps are fully clean and no contamination or cross contamination of samples will occur. After conditioning, the Desorption tubes are capped and sealed with stainless steel caps with PTFE seals until ready for use. Likewise, the desorption tube needles (transfer lines) are also conditioned before use to eliminate any possibility of cross contamination.
Air Sampling: To collect the air samples, a Gilian industrial hygiene air pump was used to pump air samples through the adsorbent traps at a rate of 100 ml/min. The pumping time was varied depending on the volume of air required for analysis. Most air testing only required 1 to 10 liters of air. In the case of the cigarette smoke, only two milliliters were required; therefore, the pumping rate was decreased to 4 ml/min and the cigarette smoke was collected for 30 seconds. The small air pump was used to trap the volatiles from all the air samples studied. It was also used to collect the cigarette smoke and fireplace smoke.
Commercial Products: For the collection of the volatiles from solid finished commercial products (such as the vinyl flooring), the Scientific Instrument Services Solid Sampling Oven was used. The samples to be analyzed were placed inside a 0.5 inch diameter by 14 inch long glass sample tube. This tube was then inserted into the sample oven, heated to 40 degrees C and purged with high purity nitrogen to drive the volatiles off the solid substrate and onto the Tenax Adsorbent traps. Samples were purged for 20 to 30 minutes at a flow rate of 20 ml/min.
Thermal Desorption: The Desorption tube with the trapped volatiles was attached to the Short Path Thermal Desorption System and a preconditioned transfer line needle was attached to the other end of the sample tubes (Figure #1). Helium carrier gas was purged through the desorption tube at room temperature for 1.0 minute to remove any oxygen from the adsorbent resin, after which the sample was injected into the GC injection port. The two heater blocks which were set to 250 degrees C were closed around the desorption tube to ballistically heat the desorption tubes. This combination of ballistic heating and GC carrier gas through the adsorbent resin, sparged any volatiles or semi-volatile resins into the hot GC injection port where they were subsequently cryo-focused at the front of the GC guard column. The desorption process continued for 10 minutes after which the desorption blocks were opened; the sample tube was withdrawn from the GC injection port and the programming of the GC column was commenced to elute the volatiles from the GC capillary column. The total ion chromatogram for each of the samples was plotted and a complete library search of each of the peaks was made using the Wiley NBS library. Blanks were run between samples to assure no cross contamination of samples.
The following series of studies were conducted using the above described technique:
(1) Analysis of Indoor Air Samples From Various Rooms In a Domestic House
(2) Analysis of Indoor Air From Public Buildings
(3) Determination of Volatile Emissions From New Carpeting Installed In a Commercial Office and Study of the Dissipation of the Volatiles With Time
(4) Analysis of Volatiles From Combustion Sources, Including Cigarettes and Fireplaces.
(5) Analysis of Volatile Emissions From Commercial Products Including Cleaning Products, Paper, Perfume, Air Fresheners, Etc.
RESULTS AND DISCUSSION
RESIDENTIAL HOME AIR
The living room air sample (Figure #2) contained a large number of compounds including: benzene, toluene and the xylenes. In addition, several terpenes including the largest peak limonene were detected. Limonene was detected in most of the air samples analyzed. In addition to occurring naturally in citrus fruits, limonene is widely used in many commercial products including laundry soaps, cleaning products, furniture polishes, and other domestic products, as will be demonstrated later. In addition, a number of straight chain hydrocarbons from Hexane through Heptadecane were also detected, as well as several of their corresponding aldehydes. Ten liters of the living room air produced peaks corresponding to levels of detection in the parts per billion (ppb) level for most of the compounds detected in this chromatogram.
Figure 2 - Living Room Air
Six liters of air were analyzed for the kitchen air sample in Figure # 3. This sample was taken in the kitchen during the cooking of tomato sauce. In addition to the same compounds detected in the living room air sample, a large number of terpenes and sesquiterpenes were detected and identified, originating from the many spices being used in the kitchen. The largest peak in the chromatogram is still limonene which probably originates from the cleaning products used in the kitchen.
Figure 3 - Kitchen Air
Ten liter samples of air from a basement game room (Figure #4) and a finished Breezeway (Figure #5) exhibit a wide range of substituted benzene type compounds, several chlorinated hydrocarbons, several hydrocarbons, and terpenes including limonene. Many of the compounds identified originated from the vinyl flooring installed in both of these rooms. In particular, the levels of benzene and toluene were quite high in both of these samples.
Figure 4 - Basement Game Room Air
Figure 5 - Finished Breezeway Air
Fifteen liters of air from a residential garage are shown in Figure #6. A large number of substituted benzenes and hydrocarbons indicative of gasoline were identified in this sample. They originated from the automobiles and lawn equipment stored in this facility. Toluene and the Xylenes were the major compounds present in this sample.
Figure 6 - Residential Garage Air
A 3.0 liter sample of air from a recent scientific instrument trade show is illustrated in Figure # 7. Many of the same aromatics and hydrocarbons that were present in the domestic house samples were detected in this sample, but at about 4 times the concentration. The major compounds present were benzene and tetrachloroethene. In addition, benzaldehyde and naphthalene were also present in relatively high concentrations.
Figure 7 - Trade Show Air
Commercial buildings exhibited many of the same compounds present in the previous samples analyzed. Twelve liters of air from an industrial warehouse are shown in Figure # 8. Many of the same compounds routinely seen in the previous air samples were once again evident in this sample. The major peaks present were Trichloroethane and toluene. Eighteen liters of air from the kitchen area of a commercial building are shown in Figure # 9. A few furan base compounds which probably originated from coffee brewing in this area were detected in this sample.
Figure 8 - Industrial Warehouse Air
Figure 9 - Lunch Area of Commercial Building Air
Figure #10 is the air sample from a restaurant. Many of the same volatile organics present in domestic kitchen air are present in this sample-with the exception of the naphthalene. The major components were limonene and toluene.
Figure 10 - Restaurant Air
Figure #11 is the result of sampling 300 ml of air at the window on the drivers side of the car while it was being serviced at a gas station. This sample was taken during the winter, when the outside air temperature was less than 30 degrees F. The lack of higher boiling compounds is evident due to this low temperature. The compounds identified include a large number of substituted benzenes and hydrocarbons indicative of gasoline.
Figure 11 - Drivers Side of Car - Air From Window While Being Serviced At a Gas Station
VOLATILES FROM NEWLY INSTALLED INDOOR CARPETING
Figure 12 - Commercial Office Air After New Carpet Installation
Figure #12 is the total ion chromatogram of 500 ml of air from a commercial office after the installation of new indoor carpeting. The carpet was installed using glue to hold it in place. Before this sample was analyzed, 100 nanogram of deuterated benzene and toluene were added to the Tenax TA (TM) trap as internal standards for the quantification of the volatiles present. This air sample contains a large number of substituted cyclohexanes and benzenes which originated from the glue which was used to install the carpeting. Additional air samples were taken before the new carpet installation and subsequently every day for 60 days after the carpet was installed. The carpet was installed in the summer and the room was aired out every day to help dissipate the volatiles. The total concentration of all the volatiles present was calculated using the deuterated internal standards as a concentration reference. The results of the total volatiles present in the office air were then plotted for each day (Figure 13). It took more than 20 days for the total volatiles to return to the pre-carpet installation levels. Had this new carpet installation occurred in the winter, when the building would be more tightly closed, this process would have taken much longer.
Figure 13 - Volatiles In Air After Carpet Installation
CIGARETTES AND COMBUSTION PRODUCTS
The smoke from a cigarette was analyzed (Figure 14). Only 2.0 ml of air were required for this sample. This was an unfiltered cigarette. The nicotine peak is the major peak and was present in the parts per hundred level (pph). The second hand smoke from cigarettes has recently come under renewed attack . This technique will accurately detect and identify the emissions from cigarettes and will prove to be a useful technique.
Figure 14 - Air From Cigarette Smoke
Smoke from a fireplace was analyzed (Figure 15). Forty milliliters of air were collected from above the fire in a residential fireplace. The fire was burning for about 1 hour and was hot when this sample was taken. As expected, a large number of substituted phenols from the combustion of the fire wood were identified. In addition high levels of Benzene, Toluene and xylenes were also detected.
Figure 15 - Smoke From a Fireplace
Volatiles and semi-volatiles from the solid commercial products were analyzed by first placing the solid sample into the S.I.S. Solid Sampling Oven, purging the sample with high purity nitrogen and trapping the volatiles on Tenax adsorbent traps. A purge and trap apparatus could also have been used to purge and trap these volatiles; however, the Solid Sampling Oven is much more efficient at purging the semi-volatiles from solid matrix samples.
The volatiles emitted from fourteen grams of vinyl flooring are shown in Figure # 16. This was plain vinyl flooring without any glue. The major peaks identified include 2,3-Butanedione, benzaldehyde, and naphthalene. Additionally, a large number of substituted benzenes and hydrocarbons were also identified in this sample.
Figure 16 - Volatiles Emitted from Vinyl Flooring
Another common source of indoor air contamination are paints. Most paints used today are latex paints. As shown in Figure # 17, these products produce significant levels of volatiles, including hydrocarbons and aromatics. The sample analyzed was only the volatiles emitted from 7 nanograms of the liquid latex paint.
Figure 17 - Air from Liquid Latex Paint
Residential Air Fresheners (Figure 18) and Perfumes (Figure 19) are also sources of indoor air contamination. Both of these products contain a diverse variety of terpenes and sesquiterpenes originating from natural sources such as flower extracts. Limonene is a major component in both of these products.
Figure 18 - Residential Air Fresheners
Figure 19 - Volatiles Emitted From Perfume
Many other household products including Furniture Polish (Figure 20) and Household laundry soap (Figure 21) also exhibit a large number of volatile emissions. The furniture polish contained large quantities of branched chain hydrocarbons and terpenes of which limonene was the major component. The laundry soap sample also exhibited a large number of terpene type compounds including limonene and camphor.
Figure 20 - Emissions From Furniture Polish
Figure 21 - Volatile Emissions From Household Laundry Soap
Paper products also are a major source of volatile emissions in the indoor air environment. Figure # 22 shows the volatile emissions from a paper table cloth. The table cloth was sealed in a plastic bag. When opened, a strong, rancid odor was evident. Subsequent analysis of the 300 ml of air from inside the package indicated high levels of aldehydes and their corresponding acids which undoubtedly were the source of the rancid odor. There appears to be a paper rancidity problem with this product. A sample of the volatile emissions from a magazine paper is shown in Figure # 23. The major peak in this sample was toluene and several substituted benzenes, probably originating from the inks or paper finishing products.
Figure 22 - Volatiles Emitted From a Paper Table Cloth
Figure 23 - Volatile Emissions From a Magazine Paper
Many products which are used in the home and workplace are responsible for contributing to the levels of volatiles in the indoor air environment. A large number of aromatics, hydrocarbons, halogenated hydrocarbons, phenols, furans, terpenes and sesquiterpenes are emitted from these products. Individually, the contribution from any one product may not be significant. However, the cumulative levels of emissions from these products are increasingly becoming a major concern. This is particularly noteworthy in the new energy efficient construction which minimizes air exchange due to the tight construction of these buildings. In the future, the levels and extent of the volatile organics in indoor air will come under closer scrutiny by both the public and scientific communities. The technique of trapping the volatiles as well as the semi-volatiles on Tenax TA (TM) adsorbent traps and the subsequent analysis using the Short Path Thermal Desorption System has proven to be a useful technique for the analysis of indoor air samples as well as the products which are the sources of indoor air contamination.
Yttria coated filament at start
Yttria coated filament after 16,000 cycles